Reddy, Pattubala A. N. ; Nethaji, Munirathinam ; Chakravarty, Akhil R. (2003) Supramolecular self assembly of a monomeric copper(II) complex of N-salicylidene-2-methoxyaniline forming three-dimensional closed and open channels Inorganica Chimica Acta, 6 (6). pp. 698-701. ISSN 0020-1693
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13877...
Related URL: http://dx.doi.org/10.1016/S1387-7003(03)00090-X
Abstract
A binary copper(II) complex [CuL2] (1), where HL is the Schiff base N-salicylidene-2-methoxyaniline, was prepared and structurally characterized. The complex which crystallizes in cubic space group Ia-3d with an unit cell dimension of 31.2451(17) Å, V=30503(3) Å3, Z=48, and refined to R-value of 0.0379 for 1700 data with I>2σ(I), shows a distorted four coordinate structure with a CuN2O2 chromophore. The complex self-assembles into a supramolecular architecture by non-covalent C-HO interactions forming open and closed channels.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Copper(II) complex; Schiff base; X-ray structure; Supramolecular architecture; Lattice channels |
| ID Code: | 6355 |
| Deposited On: | 20 Oct 2010 08:51 |
| Last Modified: | 27 May 2011 05:01 |
Repository Staff Only: item control page
