Chandrasekhar, S. ; Raji Reddy, Ch. ; Jagadeeshwar Rao, R. (2001) Unprecedented direct conversion of N-N and N=N bonds to N-(tert-butyloxy)-carbamates Synlett, 2001 (10). pp. 1561-1562. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-2001-17439
Abstract
For the first time a one step direct conversion of aromatic hydrazines and azo compounds to N-(tert-butoxycarbonyl) amines is achieved via reductive cleavage of N-N and N=N bonds using the inexpensive and safe hydride source polymethylhydrosiloxane (PMHS) and di-tert-butyl dicarbonate [(Boc)2O] in the presence of a catalytic amount of 10% Pd-C.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Polymethylhydrosiloxane; Hydrazines; Azo Compounds; Tert-butyl Carbamates; One-pot Reaction |
| ID Code: | 63498 |
| Deposited On: | 29 Sep 2011 04:16 |
| Last Modified: | 29 Sep 2011 04:16 |
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