Highly efficient cleavage of epoxides catalyzed by B(C6F5)3

Chandrasekhar, S. ; Raji Reddy, Ch. ; Nagendra Babu, B. ; Chandrashekar, G. (2002) Highly efficient cleavage of epoxides catalyzed by B(C6F5)3 Tetrahedron Letters, 43 (21). pp. 3801-3803. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)00703-7

Abstract

A highly effective protocol for ring opening of epoxides with allyl and propargyl alcohols, aniline and thiophenol in the presence of catalytic amounts of B(C6F5)3 has been developed. Benzyl, tetrahydropyranyl, tert-butyldimethyl silyl protecting groups were stable under the reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Amino Alcohols; Catalysts; Cleavage Reactions; Epoxides; Hydroxy Ethers; Hydroxy Sulfides
ID Code:63491
Deposited On:29 Sep 2011 04:18
Last Modified:29 Sep 2011 04:18

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