Chandrasekhar, S. ; Raji Reddy, Ch. ; Nagendra Babu, B. (2002) Rapid defunctionalization of carbonyl group to methylene with polymethylhydrosiloxane-B(C6F5)3 Journal of Organic Chemistry, 67 (25). pp. 9080-9082. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0204045
Related URL: http://dx.doi.org/10.1021/jo0204045
Abstract
The polymethylhydrosiloxane-B(C6F5)3 combination is found to be a versatile carbonyl defunctionalization system under mild and rapid conditions. For the first time, B(C6F5)3 has been used as a nonconventional Lewis acid catalyst to activate PMHS. Aromatic and aliphatic carbonyl compounds were effectively reduced to give the corresponding alkanes in high yields.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 63488 |
| Deposited On: | 29 Sep 2011 04:18 |
| Last Modified: | 29 Sep 2011 04:18 |
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