Shivaiaha, Vaddypally ; Arumuganathana, T. ; Das, Samar K. (2004) Chirality of a Strandberg-type heteropolyanion [S2Mo5O23]4- Inorganic Chemistry Communications, 7 (3). pp. 367-369. ISSN 1387-7003
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.inoche.2003.12.015
Abstract
The heteropolyanion [S2Mo5O23]4- having C2 symmetry is dissymmetric and hence expected to be chiral. The heteropoly-compound [NMe4]4[S2Mo5O23] exhibits its both enantiomers in DMSO solution by a Pfeiffer effect when l- and d-arabinose are used as environment substances.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Strandberg Type Heteropolyanion; Recemic Mixtures; Circular Dichroism Studies; Pfeiffer Effect |
| ID Code: | 63412 |
| Deposited On: | 29 Sep 2011 04:24 |
| Last Modified: | 29 Sep 2011 04:24 |
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