Paramagnetic keplerate "Necklaces" synthesized by a novel room-temperature solid-state reaction: controlled linking of metal-oxide-based nanoparticles

Müller, Achim ; Das, Samar K. ; Talismanova, Marina O. ; Bögge, Hartmut ; Kögerler, Paul ; Schmidtmann, Marc ; Talismanov, Sergei S. ; Luban, Marshall ; Krickemeyer, Erich (2002) Paramagnetic keplerate "Necklaces" synthesized by a novel room-temperature solid-state reaction: controlled linking of metal-oxide-based nanoparticles Angewandte Chemie (English Edition), 41 (4). pp. 579-582. ISSN 0570-0833

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/1521-37...

Related URL: http://dx.doi.org/10.1002/1521-3773(20020215)41:4<579::AID-ANIE579>3.0.CO;2-Z

Abstract

Crystal engineering with nanoobjects? Spherical structurally well-defined molybdenum-oxide-based giant clusters can be appropriately functionalized to a crystalline material with the remarkable property of having discrete cluster units which get covalently linked to form chains (see picture) through Fe-O-Mo bonds after having approached each other as a result of the release of crystal water upon drying.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Composites; Magnetic Properties; Molybdenum; Polyoxometalates; Supramolecular Chemistry
ID Code:63405
Deposited On:29 Sep 2011 04:22
Last Modified:29 Sep 2011 04:22

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