Supriya, Sabbani ; Das, Samar K. (2007) Reversible single crystal to single crystal transformation through Fe-O (H) Me/Fe-OH2 bond formation/bond breaking in a gas-solid reaction at an ambient condition Journal of the American Chemical Society, 129 (12). pp. 3464-3465. ISSN 0002-7863
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja067572p
Related URL: http://dx.doi.org/10.1021/ja067572p
Abstract
A single crystal of an iron compound containing a Fe-OH2 bond, on exposure to methanol vapor at an ambient condition, transforms to another single crystal with the formation of a Fe-O(H)Me covalent bond at the cost of breaking the Fe-OH2 bond. The methanol complex, upon exposure to atmospheric water vapor at room temperature, goes back to an original water-coordinated complex. The full reversibility of this gas-solid system was established by X-ray crystallography and IR spectroscopy.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 63398 |
| Deposited On: | 29 Sep 2011 04:30 |
| Last Modified: | 29 Sep 2011 04:30 |
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