Self-assembly of a fluorescent chiral zinc (II) complex that leads to supramolecular helices

Prabhakar, Maddela ; Zacharias, Panthapally S. ; Das, Samar K. (2005) Self-assembly of a fluorescent chiral zinc (II) complex that leads to supramolecular helices Inorganic Chemistry, 44 (8). pp. 2585-2587. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic048236h

Related URL: http://dx.doi.org/10.1021/ic048236h

Abstract

The chiral Zn(II) complex [ZnLCl2], 1 {L = 4-methyl-2,6-di[(S)-(+)-1-phenylethyliminomethyl] phenol}, self-assembles via C-H···Cl hydrogen bonding into supramolecular helices. Complex 1 exhibits emission in solution at room temperature in the visible range. Crystal data for 1: orthorhombic space group P212121, α = 9.614(2) Å, b = 13.825(3) Å, c = 18.667(3) Å, V = 2481.1(8) Å3, Z = 4.

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Deposited On:29 Sep 2011 04:25
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