Madhu, Vedichi ; Das, Samar K. (2006) A new approach to functionalize an organic compound through the influence of metal bis (dithiolene) complexes leading to ion-pair compounds exhibiting strong emission at room temperature in the visible region Inorganic Chemistry, 45 (25). pp. 10037-10039. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic0615980
Related URL: http://dx.doi.org/10.1021/ic0615980
Abstract
The facile oxidation of 6,12-dihydrodipyrido [1,2-α;1',2'-d] pyrazidinium (DDP2+ = [C12H12N2]2+) chloride to cyclic quaternary ammonium monocation, 12-oxo-9H-dipyrido[1,2-α;1',2'-d]pyrazin-5-ium (ODP1+ = [C12H9N2O]1+) is achieved when it reacts with [M(mnt)2]2- (M=Ni2+ and Cu2+) resulting in the formation of the ion pair compounds [ODP]2[Ni(mnt)2] (1) and [ODP]2[Cu(mnt)2] (2), respectively (see Scheme 1 for the structures of [ODP]1+ and [DDP]2+). The nickel complex 1 exhibits intense emission at room temperature in the visible region, whereas, in the case of copper analogue 2, the emission gets quenched. The oxo cation ODP (known to be an unstable species and never characterized unequivocally before) is stabilized in 1 and 2 by cation-anion interactions.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 63388 |
| Deposited On: | 29 Sep 2011 04:29 |
| Last Modified: | 29 Sep 2011 04:29 |
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