Yadav, J. S. ; Reddy, B. V. S. ; Krishnam Raju, A. (2003) [Bmim]BF4 ionic liquid: a novel and recyclable reaction media for the synthesis of homoallylic amines Synthesis, 2003 (6). 0883-0886. ISSN 0039-7881
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-2003-38697
Abstract
The imines derived in situ from aldehydes and amines undergo smoothly nucleophilic addition with allyltributylstannane in 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim]BF4) ionic liquid to afford the corresponding homoallylic amines in high yields with high selectivity. The recovered ionic liquid can be recycled in four to five runs with gradual decrease in activity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Allylation; Ionic Liquids; Imines; Homoallylic Amines |
| ID Code: | 63240 |
| Deposited On: | 28 Sep 2011 03:20 |
| Last Modified: | 28 Sep 2011 03:20 |
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