Bi(OTf)3-catalyzed acylation of p-quinones: a facile synthesis of acylated hydroquinones

Yadav, J. S. ; Subba Reddy, B. V. ; Swamy, T. ; Raghavender Rao, K. (2004) Bi(OTf)3-catalyzed acylation of p-quinones: a facile synthesis of acylated hydroquinones Tetrahedron Letters, 45 (31). pp. 6037-6039. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2004.06.032

Abstract

p-Quinones undergo smooth acylation with acetic anhydride in the presence of 2 mol % of bismuth triflate under mild conditions to afford the corresponding 1,4-diacylated-2-acetoxylated hydroquinones in excellent yields with high selectivity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:p-Quinones; Acid Anhydride; Thiele-Winter Reaction; Bismuth Triflate
ID Code:63230
Deposited On:28 Sep 2011 03:23
Last Modified:28 Sep 2011 03:23

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