Copper(II) triflate immobilized in [bmim]BF4 ionic liquid: an efficient reaction medium for Michael addition of β-ketoesters to acceptor-activated alkenes

Yadav, J. S. ; Reddy, B. V. S. ; Baishya, Gakul ; Venkat Narsaiah, A. (2005) Copper(II) triflate immobilized in [bmim]BF4 ionic liquid: an efficient reaction medium for Michael addition of β-ketoesters to acceptor-activated alkenes Chemistry Letters, 34 (1). pp. 102-103. ISSN 0366-7022

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Official URL: http://www.jstage.jst.go.jp/article/cl/34/1/34_102...

Related URL: http://dx.doi.org/10.1246/cl.2005.102

Abstract

1,3-Dicarbonyl compounds undergo smooth conjugate addition to α,β-unsaturated ketones in the presence of 10 mol % copper(II) triflate immobilized in air and moisture stable [bmim]BF4 ionic liquid under extremely mild conditions to afford the corresponding Michael adducts in high to quantitative yield.

Item Type:Article
Source:Copyright of this article belongs to Chemical Society of Japan.
ID Code:63226
Deposited On:28 Sep 2011 03:25
Last Modified:28 Sep 2011 03:25

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