Gallium(III) chloride catalyzed stereoselective synthesis of E-configured α,β-unsaturated ketones

Yadav, J. S. ; Subba Reddy, B. V. ; Gupta, Manoj K. ; Dash, Uttam ; Pandey, Sushil K. (2007) Gallium(III) chloride catalyzed stereoselective synthesis of E-configured α,β-unsaturated ketones Synlett, 2007 (5). 0809-0811. ISSN 0936-5214

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-2007-970760

Abstract

A simple and highly stereoselective method has been developed for the synthesis of E-configured α,β-unsaturated ketones using gallium(III) chloride as a novel catalyst. This new procedure offers significant advantages such as high conversions, short reaction times and enhanced E-selectivity together with mild reaction conditions.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Activated Alkynes; Gallium(III) Chloride; Ynones; α,β-unsaturated Ketones
ID Code:63213
Deposited On:28 Sep 2011 03:29
Last Modified:28 Sep 2011 03:29

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