Yadav, Jhillu Singh ; Madhava Rao, Batta ; Sanjeeva Rao, Kodepelly (2009) Total synthesis of 8-methoxygoniodiol related compounds via chiron approach Tetrahedron: Asymmetry, 20 (15). pp. 1725-1730. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2009.05.034
Abstract
The stereoselective synthesis of 8-methoxygoniodiol related compounds was accomplished by using readily available δ-gluconolactone as a chiral source. The stereoselective addition of an aryl Grignard reagent on an aldehyde, stereoselective reduction of a keto group and regioselective opening of a chiral epoxide by ethyl propiolate are the key steps involved in this synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 63178 |
| Deposited On: | 28 Sep 2011 03:41 |
| Last Modified: | 28 Sep 2011 03:41 |
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