Sabitha, Gowravaram ; Gopal, Peddabuddi ; Yadav, Jhillu S. (2009) Stereoselective total synthesis of polyketide lactone,(3R, 4S, 5S, 9S)-3, 5, 9-trihydroxy-4-methylundecanoic acid [delta]-lactone Tetrahedron: Asymmetry, 20 (13). pp. 1493-1499. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2009.06.008
Abstract
The total synthesis of lactone 1 has been described. The convergent asymmetric synthesis relies on the use of an Evans' syn-aldol, chain extension with lithio tert-butyl acetate, and the stereoselective reduction of a ketone as the key reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 63176 |
| Deposited On: | 28 Sep 2011 03:41 |
| Last Modified: | 28 Sep 2011 03:41 |
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