A concise and efficient synthesis of (5R,7S)-kurzilactone and its (5S,7R)-enantiomer by the Mukaiyama aldol reaction

Sabitha, Gowravaram ; Gopal, Peddabuddi ; Nagendra Reddy, C. ; Yadav, Jhillu S. (2009) A concise and efficient synthesis of (5R,7S)-kurzilactone and its (5S,7R)-enantiomer by the Mukaiyama aldol reaction Synthesis, 19 . pp. 3301-3304. ISSN 0039-7881

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Official URL: https://www.thieme-connect.com/ejournals/abstract/...

Related URL: http://dx.doi.org/10.1055/s-0029-1216936

Abstract

Natural kurzilactone (5R,7S) and its (5S,7R)-enantiomer were synthesized by a convergent approach using a diastereoselective Mukaiyama aldol reaction to construct the anti diol unit. Finally, a ring-closing metathesis reaction led to the target molecule.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Kurzilactone; Mukaiyama Reaction; Aldol Reaction; Ring Closure; Metathesis
ID Code:63174
Deposited On:28 Sep 2011 03:39
Last Modified:28 Sep 2011 03:39

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