Yadav, J. S. ; Subba Reddy, B. V. ; Mishra, Anand Kumar (2010) Zinc-mediated alkylation and acylation of 1,3-dicarbonyl compounds Chemistry Letters, 39 (3). p. 280. ISSN 0366-7022
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Official URL: http://www.jstage.jst.go.jp/article/cl/39/3/39_280...
Related URL: http://dx.doi.org/10.1246/cl.2010.280
Abstract
1,3-Dicarbonyl compounds undergo smooth allylation, benzylation, propargylation, and acylation with halides using metallic zinc in DMF at 60°C to afford the corresponding allyl, benzyl, 2-propynyl, and acylated 1,3-diesters in good yields. In the case of cyclic 1,3-diketones, the corresponding enol ethers are obtained as sole products instead of C-alkylation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Chemical Society of Japan. |
| ID Code: | 63156 |
| Deposited On: | 28 Sep 2011 03:46 |
| Last Modified: | 28 Sep 2011 03:46 |
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