Nagaiah, Kommu ; Srinivasu, Khandregula ; Praveen Kumar, S. ; Basha, Jeelani ; Yadav, Jhillu Singh (2010) Stereoselective synthesis of (S,S)-palythazine from D-mannitol Tetrahedron: Asymmetry, 21 (7). pp. 885-889. ISSN 0957-4166
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetasy.2010.05.002
Abstract
Exploiting the symmetry element, an asymmetric synthesis of (S,S)-palythazine was accomplished with (R)-glyceraldehyde acetonide as the chiral precursor. The prominent steps involved stereoselective Barbier allylation, ring-closing metathesis, regioselective nucleophilic opening of epoxide, and auto-condensation of aminoketone moiety.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 63146 |
| Deposited On: | 28 Sep 2011 03:48 |
| Last Modified: | 28 Sep 2011 03:48 |
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