Enantioselective synthesis of (+)-sedamine and (−)-allosedamine

Yadav, J. S. ; Sridhar Reddy, M. ; Purushothama Rao, P. ; Prasad, A. R. (2006) Enantioselective synthesis of (+)-sedamine and (−)-allosedamine Synthesis, 2006 (23). pp. 4005-4012. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2006-950331

Abstract

Two different approaches to the enantioselective syntheses of (+)-sedamine and (−)-allosedamine are described, both using the Sharpless asymmetric epoxidation as the key step. Regioselective reduction of epoxides, chemoselective oxidation of alcohols, ring-closing metathesis, and nucleophilic displacements were the other key steps employed.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Alkaloids; Asymmetric Synthesis; Regioselective Reduction; Ring-closing Metathesis
ID Code:63130
Deposited On:28 Sep 2011 03:27
Last Modified:28 Sep 2011 03:27

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