Yadav, J. S. ; Sridhar Reddy, M. ; Purushothama Rao, P. ; Prasad, A. R. (2006) Enantioselective synthesis of (+)-sedamine and (−)-allosedamine Synthesis, 2006 (23). pp. 4005-4012. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2006-950331
Abstract
Two different approaches to the enantioselective syntheses of (+)-sedamine and (−)-allosedamine are described, both using the Sharpless asymmetric epoxidation as the key step. Regioselective reduction of epoxides, chemoselective oxidation of alcohols, ring-closing metathesis, and nucleophilic displacements were the other key steps employed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Alkaloids; Asymmetric Synthesis; Regioselective Reduction; Ring-closing Metathesis |
| ID Code: | 63130 |
| Deposited On: | 28 Sep 2011 03:27 |
| Last Modified: | 28 Sep 2011 03:27 |
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