Yadav, Jhillu S. ; Reddy, B. V. S. ; Gupta, Manoj Kumar ; Eeshwaraiah, B. (2005) CeCl3·7H2O/NaI-promoted stereoselective aldol coupling of α,β-acetylenic ketones Synthesis, 2005 (1). pp. 57-60. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2004-834909
Abstract
A simple and highly stereoselective method has been developed for the synthesis of (Z)-β-iodo Baylis-Hillman adducts using CeCl3·7H2O/NaI as an inexpensive and readily available reagent system. High conversions and enhanced Z-selectivity together with the environmentally benign nature of the CeCl3/NaI reagent system makes this method an attractive alternative to established methods.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Cerium Compounds; Three Component Reaction; β-iodovinyl Ketones |
| ID Code: | 63124 |
| Deposited On: | 28 Sep 2011 03:25 |
| Last Modified: | 28 Sep 2011 03:25 |
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