Stereoselective synthesis of the C-21 to C-27 segment of rifamycin-S

Rama Rao, A. V. ; Yadav, J. S. ; Vidyasagar, V. (1985) Stereoselective synthesis of the C-21 to C-27 segment of rifamycin-S Journal of the Chemical Society - Series Chemical Communications (2). pp. 55-56. ISSN 0022-4936

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Official URL: http://xlink.rsc.org/?doi=C39850000055

Related URL: http://dx.doi.org/10.1039/C39850000055

Abstract

An efficient synthesis of the ansa chain of rifamycin-S corresponding to the C-21 to C-27 segment is described, starting from a bicyclic precursor endo,endo-2,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one.

Item Type:Article
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ID Code:63122
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