Total synthesis of 8-methoxygoniodiol via chiron approach

Yadav, J. S. ; Madhava Rao, B. ; Sanjeevarao, K. ; Subba Reddy, B. V. (2008) Total synthesis of 8-methoxygoniodiol via chiron approach Synlett, 2008 (7). pp. 1039-1041. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2008-1072511

Abstract

A stereoselective synthesis of 8-methoxygoniodiol is accomplished using readily available δ-gluconolactone as a chiral source. The stereoselective addition of aryl Grignard reagent on aldehyde and regioselective opening of chiral epoxide by ethyl propiolate are the key steps involved in this synthesis.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Goniodiol; δ-gluconolactone; Chiron Approach; Chiral Epoxide
ID Code:63118
Deposited On:28 Sep 2011 03:35
Last Modified:28 Sep 2011 03:35

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