Yadav, J. S. ; Raghavendra Rao, K. V. ; Ravindar, K. ; Subba Reddy, B. V. (2010) Total synthesis of (+)-aculeatin D and (+)-6-epi-aculeatin D Synlett, 2010 (1). pp. 51-54. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0029-1218546
Abstract
The stereoselective total synthesis of spiroketal natural product (+)-aculeatin D and unnatural (+)-6-epi-aculeatin D has been accomplished. Sharpless kinetic resolution of secondary allylic alcohol and phenyliodine(III) bis(trifluoroacetate) (PIFA)-mediated oxidative spirocyclization were used as key steps in this synthesis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | (+)-aculeatin D; (+)-6-epi-aculeatin D; Sharpless Kinetic Resolution; Spirocylization |
| ID Code: | 63097 |
| Deposited On: | 28 Sep 2011 03:45 |
| Last Modified: | 28 Sep 2011 03:45 |
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