Cerium(III) chloride heptahydrate-lithium iodide: a novel reagent system for the synthesis of N-arylpyrrolidines

Yadav, J. S. ; Subba Reddy, B. V. ; Narasimhulu, G. ; Chandrakanth, D. ; Satheesh, G. (2009) Cerium(III) chloride heptahydrate-lithium iodide: a novel reagent system for the synthesis of N-arylpyrrolidines Synthesis, 2009 (20). pp. 3443-3448. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-0029-1216970

Abstract

Aldimines, generated in situ from arylamines and aryl aldehydes, undergo smooth cycloaddition with cyclopropane-1,1-dicarboxylate in the presence of the cerium(III) chloride heptahydrate-lithium iodide reagent system in refluxing acetonitrile under neutral conditions to produce the corresponding N-arylpyrrolidines in good yields with high selectivity.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Cerium(III) Reagents; Aldimines; Cyclopropanedicarboxylate; Pyrrolidines; Cycloadditions; Ring Expansion
ID Code:63087
Deposited On:28 Sep 2011 03:40
Last Modified:28 Sep 2011 03:40

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