Yadav, J. S. ; Subba Reddy, B. V. ; Venkateshwara Rao, C. ; Chand, P. K. ; Prasad, A. R. (2002) A facile and selective cleavage of Prenyl esters catalyzed by CeCl3·7H2O-NaI Synlett, 2002 (1). 0137-0139. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2002-19320
Abstract
A highly selective cleavage of prenyl esters has been achieved in high yields using CeCl3·7 H2O-NaI in refluxing acetonitrile under neutral conditions. This method is mild and compatible with a wide variety of functional groups such as BOC, Cbz, acetate, allyl, benzyl, tetrahydropyranyl, PMB ethers, allyl, methyl, and benzyl esters present in the molecule.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Cerium Reagents; 3-methylbut-2-enoate; α-amino Acids |
| ID Code: | 63054 |
| Deposited On: | 28 Sep 2011 03:18 |
| Last Modified: | 28 Sep 2011 03:18 |
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