Total synthesis of (+)-cryptocaryalactone and of a diastereoisomer of (+)-strictifolione via ring-closing metathesis (RCM) and olefin cross-metathesis (CM)

Sabitha, Gowravaram ; Vangala, Bhaskar ; Siva Sankara Reddy, S. ; Yadav, Jhillu S. (2010) Total synthesis of (+)-cryptocaryalactone and of a diastereoisomer of (+)-strictifolione via ring-closing metathesis (RCM) and olefin cross-metathesis (CM) Helvetica Chimica Acta, 93 (2). pp. 329-338. ISSN 0018-019X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/hlca.20...

Related URL: http://dx.doi.org/10.1002/hlca.200900170

Abstract

Ring-closing metathesis (RCM) and olefin cross-metathesis (CM) reactions were used as the key steps for the synthesis of (+)-cryptocaryalactone (1) and the first synthesis of the diastereoisomer 3 of (+)-strictifolione, starting from the commercially available L-malic acid (=(2S)-2-hydroxybutanedioic acid).

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
Keywords:Ring-closing Metathesis; Olefin Cross-metathesis; Strictifolione; Cryptocaryalactone; Grubbs catalyst
ID Code:62873
Deposited On:24 Sep 2011 05:01
Last Modified:24 Sep 2011 05:01

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