Yadav, J. S. ; Gopala Rao, Y. ; Ravindar, K. ; Subba Reddy, B. V. ; Narsaiah, A. V. (2009) Total synthesis of xestodecalactone C from L-malic acid Synthesis, 2009 (18). pp. 3157-3161. ISSN 0039-7881
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-0029-1216938
Abstract
An efficient total synthesis of the ten-membered macrolide, xestodecalactone C is described. The synthetic sequence uses Barbier-allylation, LiAlH4/LiI-mediated syn-stereoselective 1,3-asymmetric reduction, and intramolecular Friedel-Crafts acylation as key steps.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Xestodecalactone C; Barbier Allylation; Stereoselective Reduction; Intramolecular Friedel-Crafts Acylation |
| ID Code: | 62868 |
| Deposited On: | 24 Sep 2011 04:59 |
| Last Modified: | 24 Sep 2011 04:59 |
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