From vinylpyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization

Hung Mac, Dinh ; Samineni, Ramesh ; Petrignet, Julien ; Srihari, Pabbaraja ; Chandrasekhar, Srivari ; Yadav, Jhillu Singh ; Grée, René (2009) From vinylpyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization Chemical Communications (31). pp. 4717-4719. ISSN 0009-241X

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Official URL: http://xlink.rsc.org/?doi=b907632h

Related URL: http://dx.doi.org/10.1039/B907632H

Abstract

Starting from vinyl pyranoses an iron-catalyzed tandem isomerization-intramolecular aldolization reaction was developed to prepare cyclohexenone derivatives bearing substituents on the double bond, and it has been applied in a short synthesis of 4-epi-gabosines A and B, from D-glucose.

Item Type:Article
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ID Code:62853
Deposited On:24 Sep 2011 05:05
Last Modified:24 Sep 2011 05:05

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