Iron (III) chloride as mild and efficient reagent for the α-thiocyanation of ketones: an expedient synthesis of α-oxo thiocyanates

Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Subba Reddy, Ummareddy V. ; Chary, Darshanoju N. (2008) Iron (III) chloride as mild and efficient reagent for the α-thiocyanation of ketones: an expedient synthesis of α-oxo thiocyanates Synthesis, 2008 (8). pp. 1283-1287. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2008-1072517

Abstract

A simple and efficient method for the α-thiocyanation of ketones has been developed; anhydrous iron(III) chloride is used under mild conditions to produce α-oxo thiocyanates in good to high yields and with high selectivity. The use of inexpensive and readily available iron(III) chloride makes this procedure simple, convenient, and practical.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Thiocyanation; Ketones; Iron(III) Chloride; Catalysis; α-oxo Thiocyanates
ID Code:62836
Deposited On:24 Sep 2011 04:56
Last Modified:24 Sep 2011 04:56

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