Yadav, J. S. ; Raghavendra, S. ; Satyanarayana, M. ; Balanarsaiah, E. (2005) Phosphomolybdic acid supported on silica gel: an efficient, mild and reusable catalyst for the chemoselective hydrolysis of acetonides Synlett, 2005 (16). pp. 2461-2464. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2005-872701
Abstract
Carbohydrate acetonides were chemoselectively cleaved to the corresponding diols by using environmentally benign phosphomolybdic acid (H3PMo12O40) supported on silica gel (PMA-SiO2) at ambient temperature in a short span of 5-7 minutes in acetonitrile. Acid-labile protective groups such as THP, TBS, TBDPS, MOM, OMe and PMB were found to be stable under the reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Acetonides; Phosphomolybdic Acid; Chemoselective Hydrolysis; Silica Gel |
| ID Code: | 62832 |
| Deposited On: | 24 Sep 2011 04:49 |
| Last Modified: | 24 Sep 2011 04:49 |
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