Yadav, Jhillu. S. ; Subba Reddy, Basi V. ; Srinivas, C. ; Srihari, P. (2001) Ultrasound-promoted deoxygenation of sulphoxides by samarium - NH4Cl Synlett, 2001 (6). 0854-0856. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2001-14911
Abstract
Several aromatic and aliphatic sulphoxides are selectively deoxygenated to the corresponding thioethers in high to quantitative yields by samarium metal in methanolic ammonium chloride under sonication. Other functional groups such as halides, esters, ethers, nitriles, olefins and ketones are unaffected under the present reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Samarium; Ultrasound; Sulphoxides; Sulphides |
| ID Code: | 62817 |
| Deposited On: | 24 Sep 2011 04:37 |
| Last Modified: | 24 Sep 2011 04:37 |
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