Amberlyst-15-catalyzed novel synthesis of tetrahydropyranols

Yadav, Jhillu S. ; Subba Reddy, Basi V. ; Chandra Sekhar, Korapala ; Gunasekar, Duwuru (2001) Amberlyst-15-catalyzed novel synthesis of tetrahydropyranols Synthesis, 2001 (6). 0885-0888. ISSN 0039-7881

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2001-13412

Abstract

The cross-coupling reaction of homoallyl alcohols with aldehydes in the presence of Amberlyst-15 resulted in the formation of 4-hydroxy-2,6-disubstituted tetrahydropyrans in high yields with high diastereoselectivity. The stereochemistry of these products was assigned with the assistance of coupling constants and nOe studies.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Amberlyst-15; Prins Cyclization; Homoallyl Alcohols; Tetrahydropyranols
ID Code:62786
Deposited On:24 Sep 2011 04:37
Last Modified:24 Sep 2011 04:37

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