Yadav, J. S. ; Reddy, B. V. S. ; Venkateshwar Rao, C. ; Chand, Pratap. K. ; Prasad, A. R. (2001) Iodine-catalyzed stereoselective synthesis of allylglycosides, glycosyl cyanides and glycosyl azides Synlett, 2001 (10). pp. 1638-1640. ISSN 0936-5214
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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...
Related URL: http://dx.doi.org/10.1055/s-2001-17438
Abstract
Iodine efficiently catalyzes the glycosidation of glycals with allyltrimethylsilane, trimethylsilyl cyanide and trimethylsilyl azide in dichloromethane at ambient temperature to afford the corresponding 2,3-unsaturated allyl glycosides, glycosyl cyanides and glycosyl azides in excellent yields with high α-selectivity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Ferrier Rearrangement; Glycals; Iodine; C-glycosides |
| ID Code: | 62781 |
| Deposited On: | 24 Sep 2011 04:35 |
| Last Modified: | 24 Sep 2011 04:35 |
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