Yadav, J. S. ; Reddy, B. V. S. ; Krishna, A. D. ; Sadasiv, K. ; Janardhana Chary, Ch. (2003) Ceric (IV) ammonium nitrate: a novel reagent for the synthesis of homoallyl alcohols Chemistry Letters, 32 (3). pp. 248-249. ISSN 0366-7022
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Official URL: http://www.jstage.jst.go.jp/article/cl/32/3/32_248...
Related URL: http://dx.doi.org/10.1246/cl.2003.248
Abstract
A rapid and highly efficient method has been developed for the allylation of aldehydes with allyltributylstannane using a catalytic amount of ceric ammonium nitrate in acetonitrile under mild and neutral conditions to afford the corresponding homoallyl alcohols in excellent yields with high chemoselectivity. Allylation of ketones has also been achieved with tetraallytin under similar reaction conditions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Chemical Society of Japan. |
| ID Code: | 62776 |
| Deposited On: | 24 Sep 2011 04:43 |
| Last Modified: | 24 Sep 2011 04:43 |
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