LiBF4-mediated conversion of aldehydes to gem-diacetates

Yadav, Jhillu S. ; Reddy, Basi V. S. ; Venugopal, Chenna ; Ramalingam, T. (2002) LiBF4-mediated conversion of aldehydes to gem-diacetates Synlett, 2002 (4). 0604-0606. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2002-22705

Abstract

An efficient and highly selective method for the conversion of aldehydes to gem-diacetates is described using lithium tetrafluoroborate under mild reaction conditions. Due to the neutral reaction conditions, this method is compatible with acid-sensitive protecting groups such as acetonides, carbamates, THP and TBDMS ethers present in the substrate.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Lithium Tetrafluoroborate; Aldehydes; gem-diacetates
ID Code:62748
Deposited On:24 Sep 2011 04:42
Last Modified:24 Sep 2011 04:42

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