One-pot oxidation and wittig olefination of alcohols using o-iodoxybenzoic acid and stable wittig ylide

Maiti, Arup ; Yadav, J. S. (2001) One-pot oxidation and wittig olefination of alcohols using o-iodoxybenzoic acid and stable wittig ylide Synthetic Communications, 31 (10). pp. 1499-1506. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1081/SCC-100...

Related URL: http://dx.doi.org/10.1081/SCC-100104061

Abstract

Benylic, allylic, and propargylic alcohols, as well as diols, can be oxidized with o-iodoxybenzoic acid (IBX) in the presence of stabilized Wittig ylide[1] to generate α,β-unsaturated ester in one pot. This is useful when the intermediate aldehydes are unstable and difficult to isolate.

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