Chandrasekhar, Srivari ; Jagadeshwar, Vannada ; Saritha, Birudaraju ; Narsihmulu, Cheryala (2005) Palladium-triethylborane-triggered direct and regioselective conversion of allylic alcohols to allyl phenyl sulfones Journal of Organic Chemistry, 70 (16). pp. 6506-6507. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo0505728
Related URL: http://dx.doi.org/10.1021/jo0505728
Abstract
A combination of Pd(OAc)2 (5 mol %), PPh3 (10 mol %), and Et3B (200 mol %) promotes the formation of allyl phenyl sulfones from the allylic alcohols directly with excellent yields under mild conditions. The activation of an alcohol group is not necessary which is achieved in situ. The conjugated dienols also were equally effective for the said transformation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 62406 |
| Deposited On: | 22 Sep 2011 03:27 |
| Last Modified: | 22 Sep 2011 03:27 |
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