Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol)

Chandrasekhar, S. ; Saritha, B. ; Jagadeshwar, V. ; Narsihmulu, Ch. ; Vijay, Dolly ; Dattatreya Sarma, G. ; Jagadeesh, B. (2006) Hydroxy-assisted catalyst-free Michael addition-dehydroxylation of Baylis-Hillman adducts in poly(ethylene glycol) Tetrahedron Letters, 47 (17). pp. 2981-2984. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2006.02.104

Abstract

Intramolecular hydrogen bonding facilitates nucleophilic addition of sulfones to Baylis-Hillman adducts in a single step to realize the substituted allyl sulfones. The reaction is performed in PEG (400 MW) as solvent, which allows easy solvent recycling.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:62395
Deposited On:22 Sep 2011 03:28
Last Modified:22 Sep 2011 03:28

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