Chandrasekhar, S. ; Shameem Sultana, S. ; Kiranmai, N. ; Narsihmulu, Ch. (2007) Asymmetric synthesis of (+)-tetrahydropseudodistomin Tetrahedron Letters, 48 (13). pp. 2373-2375. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.01.143
Abstract
An efficient asymmetric synthesis of (+)-tetrahydropseudodistomin is described. The important synthetic features include a Maruoka asymmetric allylation and a Sharpless asymmetric dihydroxylation as key steps for the generation of chirality at C−2, −4, and −5 of the trisubstituted piperidine ring. Graphical abstract An efficient asymmetric synthesis of (+)-tetrahydropseudodistomin is described using the Maruoka asymmetric allylation and Sharpless asymmetric dihydroxylation as key steps for the generation of chirality at C−2, −4, and −5 of the trisubstituted piperidine ring.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Marouka Asymmetric Allylation; Sharpless Asymmetric Dihydroxylation |
| ID Code: | 62373 |
| Deposited On: | 22 Sep 2011 03:32 |
| Last Modified: | 22 Sep 2011 03:32 |
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