Asymmetric synthesis of (+)-passifloricin A and its 6-epimer

Chandrasekhar, S. ; Rambabu, Ch. ; Syamprasad Reddy, A. (2008) Asymmetric synthesis of (+)-passifloricin A and its 6-epimer Tetrahedron Letters, 49 (29-30). pp. 4476-4478. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.05.070

Abstract

Stereoselective total syntheses of the antiprotozoal natural product (+)-passifloricin A and its C-6 epimer have been achieved in ∼5% overall yield. The strategy is based on Jacobsen epoxidation, Grubbs' metathesis and an Evans' intramolecular oxa-Michael reaction.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Jacobsen Epoxidation; Grubbs' Metathesis; Evans' Intramolecular Oxa-Michael Reaction; Maruoka Allylation
ID Code:62355
Deposited On:22 Sep 2011 03:34
Last Modified:22 Sep 2011 03:34

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