From vinyl pyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization

Mac, Dinh Hung ; Samineni, Ramesh ; Petrignet, Julien ; Srihari, Pabbaraja ; Chandrasekhar, Srivari ; Yadav, Jhillu Singh ; Grée, René (2009) From vinyl pyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization Chemical Communications (London), 2009 (31). pp. 4717-4719. ISSN 0009-241X

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Official URL: http://pubs.rsc.org/en/content/articlelanding/2009...

Related URL: http://dx.doi.org/10.1039/B907632H

Abstract

Starting from vinyl pyranoses an iron-catalyzed tandem isomerization-intramolecular aldolization reaction was developed to prepare cyclohexenone derivatives bearing substituents on the double bond, and it has been applied in a short synthesis of 4-epi-gabosines A and B, from D-glucose.

Item Type:Article
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ID Code:62347
Deposited On:22 Sep 2011 03:35
Last Modified:22 Sep 2011 03:35

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