Chandrasekhar, S. ; Kiranmai, N. (2010) Asymmetric total synthesis of (+)−cardiobutanolide via an iterative asymmetric dihydroxylation in PEG Tetrahedron Letters, 51 (31). pp. 4058-4060. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.05.122
Abstract
The stereoselective total synthesis of (+)−cardiobutanolide, a polyhydroxylated natural product, is achieved in high yield through Lu and Guo diene synthesis, Sharpless asymmetric dihydroxylation, and one-pot deprotection-lactonization. The utility of a recyclable reagent system in PEG for asymmetric dihydroxylation is demonstrated.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 62331 |
| Deposited On: | 22 Sep 2011 03:37 |
| Last Modified: | 22 Sep 2011 03:37 |
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