Chandrasekhar, S. ; Balaji, S. V. ; Rajesh, G. (2010) First total synthesis of achaetolide Tetrahedron Letters, 51 (39). pp. 5164-5166. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2010.07.127
Abstract
The first total synthesis of achaetolide, a 10-membered macrolactone was achieved using Mitsunobu reaction and Grubbs ring-closing metathesis reaction as the key steps for ring construction. The desired stereo centres were generated by Jacobsen hydrolytic kinetic resolution, dihydroxylation and Sharpless asymmetric epoxidation reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 62330 |
| Deposited On: | 22 Sep 2011 03:37 |
| Last Modified: | 22 Sep 2011 03:37 |
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