Chattaraj, Pratim Kumar ; Giri, Santanab (2007) Stability, reactivity, and aromaticity of compounds of a multivalent superatom Journal of Physical Chemistry A, 111 (43). pp. 11116-11121. ISSN 1089-5639
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jp0760758
Related URL: http://dx.doi.org/10.1021/jp0760758
Abstract
In this article, we analyze the stability, reactivity, and possible aromatic behavior of two recently reported clusters (Reveles, J. U.; Khanna, S. N.; Roach, P. J.; Castleman, A. W., Jr. Proc. Natl. Acad. Sci. 2006, 103, 18405), viz., Al7C- and Al7O- in the light of the principles of the maximum hardness and minimum electrophilicity as well as the nucleus-independent chemical shift values. Stability of these clusters in the context of addition/removal of an electron or an Al atom is now clearly understood.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 6229 |
| Deposited On: | 20 Oct 2010 11:31 |
| Last Modified: | 11 May 2012 11:33 |
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