Cu(II) mediated generation and spectroscopic study of the tris(4-anisyl)amine radical cation and dication. Unusually shielded chemical shifts in the dication

Sreenath, Kesavapillai ; Thomas, Tony George ; Gopidas, Karical R. (2011) Cu(II) mediated generation and spectroscopic study of the tris(4-anisyl)amine radical cation and dication. Unusually shielded chemical shifts in the dication Organic Letters, 13 (5). pp. 1134-1137. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol103167m

Related URL: http://dx.doi.org/10.1021/ol103167m

Abstract

The reaction of tris(4-anisyl)amine (TAA) with Cu2+ ion leading to formation of the TAA radical cation and dication is described. Spectroscopic studies confirm the formation of the radical cation and dication. 1H and 13C NMR spectral studies reveal interesting structural features of the dication.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:62093
Deposited On:16 Sep 2011 04:38
Last Modified:16 Sep 2011 04:38

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