Samanta, A. ; Gopidas, K. R. ; Das, P. K. (1993) Facile electron transfer from aromatic triplets to polyaryl carbocations Chemical Physics Letters, 204 (3-4). pp. 269-272. ISSN 0009-2614
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0009-2614(93)90007-N
Abstract
The bimolecular rate constants for electron transfer from aromatic triplets to polyaryl carbocations are large and diffusion-controlled even in the limit of high exothermicity. In some cases, although the exothermicity of energy transfer is comparable to that for electron transfer, the latter dominates over the former.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 62086 |
| Deposited On: | 16 Sep 2011 04:35 |
| Last Modified: | 16 Sep 2011 04:35 |
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