Silica mesostructures: control of pore size and surface area using a surfactant-templated hydrothermal process

Ganguly, Aparna ; Ahmad, Tokeer ; Ganguli, Ashok K. (2010) Silica mesostructures: control of pore size and surface area using a surfactant-templated hydrothermal process Langmuir, 26 (18). pp. 14901-14908. ISSN 0743-7463

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Official URL: http://pubs.acs.org/doi/abs/10.1021/la102510c

Related URL: http://dx.doi.org/10.1021/la102510c

Abstract

The cooperative self-assembly of the silica precursor, tetraethyl ortho silicate (TEOS), with the surfactant molecule followed by the basic hydrolysis led to the formation of mesoporous silica with varying pore sizes. The pores are formed by the removal of the intermediate assemblies of the charged surfactant molecules. In the absence of formation of such assemblies of surfactants (example in the case of nonionic surfactants), the resulting mesostructures have very small pores, giving low surface area mesostructures. This study outlines the precise control of pore size in a wide size distribution (3.4-22 nm) by the systematic variation of the surfactant. The addition of polyethylene glycol (in situ) while carrying out the hydrolysis of TEOS results in the formation of large-sized cavities (~40 nm). Uniform spherical particles with pores (different from the cavities) as large as 22 nm and surface areas of ~1100 m2/g have been obtained by the combined effect of the hydrothermal conditions on the cetyl trimethyl ammonium bromide-templated synthesis.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:62011
Deposited On:16 Sep 2011 03:58
Last Modified:16 Sep 2011 03:58

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