Chandra, Amalendu (1998) Dynamics of electrical double layer formation at a charged solid surface Journal of Molecular Structure: Theochem, 430 (1). pp. 105-111. ISSN 0166-1280
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S01661...
Related URL: http://dx.doi.org/10.1016/S0166-1280(98)90225-1
Abstract
A theoretical study of the dynamics of electrical double layer formation near a charged solid surface is presented. A microscopic expression for the time dependent inhomogeneous charge density of an ionic solution next to a newly charged surface is derived by using linear response theory and molecular hydrodynamics. The presence of interionic correlations is included through ionic structure factors. The rate of electrical double layer formation is found to depend rather strongly on ion concentration and on the dielectric constant of the medium. It is also found that the formation of double layer becomes slower with increase in distance from the charged surface.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Electrical Double Layer; Charged Solid Surface; Dynamics |
| ID Code: | 6181 |
| Deposited On: | 19 Oct 2010 11:19 |
| Last Modified: | 19 Oct 2010 11:19 |
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