Reductive removal of allylic functional groups by nickel boride

Sarma, D. N. ; Sharma, R. P. (1985) Reductive removal of allylic functional groups by nickel boride Tetrahedron Letters, 26 (21). pp. 2581-2584. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)98842-7

Abstract

Reductive removal of an allylic functional group proceeds most easily and efficiently with nickel boride as the bond being cleaved becomes a better leaving group (e.g. OCH3<OH <OSiMe3<OCOCH3<OCOCF3).

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