Deoxygenation of vic-diols with chlorotrimethyl-silane and sodium iodide.: a new method for the synthesis of melampolide and cis, cis-germacranolide type sesquiterpene lactones

Sarma, Jadab Chandra ; Barua, Nabin Chandra ; Sharma, Ram Prakash ; Barua, Jogendra Nath (1983) Deoxygenation of vic-diols with chlorotrimethyl-silane and sodium iodide.: a new method for the synthesis of melampolide and cis, cis-germacranolide type sesquiterpene lactones Tetrahedron, 39 (17). pp. 2843-2846. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82456-X

Abstract

Deoxygenation of secondary-tertiary vic-diols with chlorotrimethylsilane and sodium iodide has been shown to be a stereospecific reaction. Application of this procedure has led to the synthesis of melampolide and cis, cis-germacranolide type sesquiterpene lactones.

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ID Code:61416
Deposited On:15 Sep 2011 03:32
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